Metal Catalyst

1.
Enantioselective Decarboxylative Arylation of α-Amino Acids via the Merger of Photoredox and Nickel Catalysis
Zuo, Z.; Cong, H.; Li, W.; Choi, J.; Fu, G. C.; MacMillan, D. W. C.
J. Am. Chem. Soc. 2016. 138 (6), 1832-1835. DOI: 10.1021/jacs.5b13211- Group: MacMillan at Princeton University
- Catalyst: Iridium (photocatalyst), Nickel
- Model: H150 Blue


4.
Alcohols as Latent Coupling Fragments for Metallaphotoredox Catalysis: sp3–sp2 Cross-Coupling of Oxalates with Aryl Halides
Zhang, X.; MacMillan, D. W. C.
J. Am. Chem. Soc. 2016. 138 (42), 13862-13865. DOI: 10.1021/jacs.6b09533- Group: MacMillan at Princeton University
- Catalyst: Iridium (photocatalyst), Nickel
- Model: H150 Blue

Figure S1 Top view. Four 34 W Kessil KSH150B Blue LED Grow Light 150 are positioned on all four sides of the box covered with aluminum foil.

Figure S2 Set-up for Screening and Isolation Scale Fluorination Reactions. Left: Isolation (left) and screening scale (right) in photocatalysis set up. Right: Screening-multiple vials per lamp, isolation-one vial per lamp.
9.
Metallaphotoredox-enabled deoxygenative arylation of alcohols
Dong, Z.; MacMillan, D. W. C.
Nature 2021. 598, 451–456. DOI: 10.1038/s41586-021-03920-6- Group: MacMillan at Princeton University
- Catalyst: Iridium (photocatalyst), Nickel
- Model: A160WE Tuna Blue
35.
Mechanistic Analysis of Metallaphotoredox C–N Coupling: Photocatalysis Initiates and Perpetuates Ni(I)/Ni(III) Coupling Activity
Till, N. A.; Tian, L.; Dong, Z.; Scholes, G. D.; MacMillan, D. W. C.
J. Am. Chem. Soc. 2020. 142 (37), 15830-15841. DOI: 10.1021/jacs.0c05901- Group: MacMillan at Princeton University
- Catalyst:Copper, Iridium (photocatalyst)
- Model: A160WE Tuna Blue
37.
A Metallaphotoredox Strategy for the Cross-Electrophile Coupling of α-Chloro Carbonyls with Aryl Halides
Chen. T. Q.; MacMillan, D. W. C.
Angew. Chem. Int. Ed. 2019. 58, 14584. DOI: 10.1002/anie.201909072- Group: MacMillan at Princeton University
- Catalyst: Iridium (photocatalyst), Nickel
- Model: A160WE Tuna Blue
Organic Catalyst

2.
The merger of decatungstate and copper catalysis to enable aliphatic C(sp3)–H trifluoromethylation
Sarver, P.J.; Bacauanu, V.; Schultz, D.M.; DiRocco, D.A.; Lam, Y.H.; Sherer, E.C.; MacMillan, D.W.C.
Nat. Chem. 2020. 12, 459–467. DOI: 10.1038/s41557-020-0436-1- Group: MacMillan at Princeton University
- Catalyst:Copper, Decatungstate (photocatalyst), Copper
- Model: PR160-390

Supplementary Figure 3. Example of reaction setup (0.5 mmol scale).

Supplementary Figure 5. UV light-shielding amber acrylic box used during reactions.
20.
Site-selective tyrosine bioconjugation via photoredox catalysis for native-to-bioorthogonal protein transformation
Li, B. X.; Kim, D. K.; Bloom, S.; Huang, R. Y.-C.; Qiao, J. X.; Ewing, W. R.; Oblinsky, D. G.; Scholes, G. D.; MacMillan, D. W. C.
Nat. Chem. 2021. 13, 902–908. DOI: 10.1038/s41557-021-00733-y- Group: MacMillan at Princeton University
- Catalyst: Lumiflavin (photocatalyst)
- Model: PR160-440
32.
Site-Selective Functionalization of Methionine Residues via Photoredox Catalysis
Kim, J.; Li, B. X.; Huang, R. Y.-C.; Qiao, J. X.; Ewing, W. R.; MacMillan, D. W. C.
J. Am. Chem. Soc. 2020. 142 (51), 21260-21266. DOI: 10.1021/jacs.0c09926- Group: MacMillan at Princeton University
- Catalyst: Lumiflavin (photocatalyst)
- Model: PR160-440

38.
The merger of decatungstate and copper catalysis to enable aliphatic C(sp3)–H trifluoromethylation
Sarver, P.J.; Bacauanu, V.; Schultz, D.M.; DiRocco, D.A.; Lam, Y.H.; Sherer, E.C.; MacMillan, D.W.C.
Nat. Chem. 2020. 12, 459–467. DOI: 10.1038/s41557-020-0436-1- Group: MacMillan at Princeton University
- Catalyst: Decatungstate (photocatalyst), Copper
- Model: PR160-390
Direct Photoexcitation
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Separator
Beyond Blue
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Separator
Photoreactor Design
4.
Rapid Optimization of Photoredox Reactions for Continuous-Flow Systems Using Microscale Batch Technology
González-Esguevillas, M.; Fernández, D. F.; Rincón, J. A.; Barberis, M.; de Frutos, O.; Carlos Mateos, C.; García-Cerrada, S.; Agejas, J.; MacMillan, D. W. C.
ACS Cent. Sci. 2021. 7 (7), 1126-1134. DOI: 10.1021/acscentsci.1c00303- Group: MacMillan at Princeton University
- Catalyst: Iridium, 4CzIPN (photocatalysts)
- Model: PR160-390, PR160-427, PR160-440, PR160-456, PR160-467
